Poly[aquabis[μ2-2-(pyridin-4-ylsulfanyl)acetato]zinc]
نویسندگان
چکیده
The crystal structure of the title complex, [Zn(C(7)H(6)NO(2)S)(2)(H(2)O)](n), consists of extended layers parallel to (001) with 2-(pyridin-4-ylsulfan-yl)acetate ligands bridging the Zn(II) atoms. The Zn(II) atom shows a distorted penta-gonal-bipyramidal coordination environment. The Zn(II) and one O atom are situated on a crystallographic twofold rotation axis. In the crystal, intra-layer O-H⋯O hydrogen-bond inter-actions help to consolidate the coordination layer.
منابع مشابه
Poly[trans-diaquabis[μ2-2-(pyridin-3-yl)acetato-κ2 N:O]zinc]
In the title coordination polymer, [Zn(C(7)H(6)NO(2))(2)(H(2)O)(2)](n), the Zn(II) cation is located on an inversion center and is coordinated by four pyridyl-acetate anions and two water mol-ecules in a distorted ZnN(2)O(4) octa-hedral geometry. The pyridine-N and carboxyl-ate-O atoms of the pyridyl-acetate anion connect to two Zn(II) cations, forming a two-dimensional polymeric complex extend...
متن کاملcatena-Poly[[[(acetato-κ2 O,O′)cadmium]-μ-acetato-κ3 O,O′:O′-μ-{1,2-bis[4-(pyridin-3-yl)pyrimidin-2-ylsulfanyl]ethane}-κ2 N 4,N 4′] trihydrate]
The title compound, {[Cd(CH(3)COO)(2)(C(20)H(16)N(6)S(2))]·3H(2)O}(n), exists as a one-dimensional zigzag polymer in which the Cd(II) ion shows a seven-coordinate [CdO(5)N(2)] distorted penta-gonal-bipyramidal geometry with the N atoms in axial positions and an N-Cd-N angle of 176.94 (13)°. The metal atoms are bridged by 1,2-bis-[4-(pyridin-3-yl)pyrimidin-2-ylsulfan-yl]ethane ligands, giving a ...
متن کاملPoly[bis[μ2-2-(1H-1,2,4-triazol-1-yl)acetato]zinc(II)]
In the title compound, [Zn(C(4)H(4)N(3)O(2))(2)](n), the Zn(II) atom is coordinated by two O atoms [Zn-O = 1.969 (2) and 1.997 (2) Å] and two N atoms [Zn-N = 2.046 (2) and 2.001 (2) Å] in a distorted tetra-hedral geometry. Non-classical inter-molecular C-H⋯O hydrogen bonds link the complex into a three-dimensional supra-molecular framework.
متن کاملTwo cadmium coordination polymers with bridging acetate and phenylenediamine ligands that exhibit two-dimensional layered structures
Poly[tetra-μ2-acetato-κ8O:O'-bis-(μ2-benzene-1,2-di-amine-κ2N:N')dicadmium], [Cd2(CH3COO)4(C6H8N2)2] n , (I), and poly[[(μ2-acetato-κ2O:O')(acetato-κ2O,O')(μ2-benzene-1,3-di-amine-κ2N:N')cadmium] hemihydrate], {[Cd(CH3COO)2(C6H8N2)]·0.5H2O} n , (II), have two-dimensional polymeric structures in which monomeric units are joined by bridging acetate and benzenedi-amine ligands. Each of the CdII io...
متن کاملPoly[[(μ2-acetato-κ3 O,O′:O′)aquabis(μ3-isonicotinato-κ3 O:O′:N)samarium(III)silver(I)] perchlorate]
The title compound, {[AgSm(C(6)H(4)NO(2))(2)(CH(3)CO(2))(H(2)O)]ClO(4)}(n), is a three-dimensional heterobimetallic complex constructed from a repeating dimeric unit. Only half of the dimeric moiety is found in the asymmetric unit; the unit cell is completed by crystallographic inversion symmetry. The Sm(III) ion is eight-coordinated by four O atoms of four different isonicotinate ligands, thre...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2011